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21.
建立了超声萃取-高效液相色谱法(HPLC)同时测定人造革中7种苯并三唑类紫外线吸收剂UV-P、UV-326、UV-327、UV-329、UV-350、UV-320和UV-328含量的方法。该方法以甲醇为萃取溶剂,超声萃取人造革中的苯并三唑类紫外线吸收剂,萃取液经处理后直接进行HPLC分析,外标法定量。在信噪比(S/N)=3的条件下,UV-P、UV-326、UV-327、UV-329、UV-350的检出限均为0.05mg/kg,UV-320、UV-328的检出限均为0.10 mg/kg。在3个不同加标浓度水平下,各组分的平均加标回收率为88.19%~98.32%,相对标准偏差(RSD)为0.61%~3.74%。该方法简便快捷、灵敏度高,可用于人造革中苯并三唑类紫外线吸收剂的测定。采用该方法对市售人造革样品进行测定,结果在6个样品中检出了不同浓度水平的UV-P和UV-329。 相似文献
22.
在超声辐射和哌啶催化反应条件下,1,3-二氢吲哚-2-酮(1)与芳香醛2a~2m发生Knoevenagel缩合反应,合成了一系列3-芳亚甲基吲哚-2-酮衍生物3a~3m。该方法具有产率高、反应时间短、后处理简单和环境友好等优点,产物通过~1H NMR、~(13)C NMR和HRMS手段进行结构表征,并通过核磁2D NOESY确定了所有化合物几何构型。初步抑菌活性测试结果表明,化合物3d对革兰氏阳性菌具有较好的抑制作用,最小抑菌浓度(MIC)为15.6μg/m L,化合物3f、3g、3h和3k对油菜菌核病菌表现出良好的抑制活性,MIC为62.5μg/m L,与阳性对照多菌灵相当。此外,对此类化合物的构效关系进行了讨论。 相似文献
23.
Srinivas Angapelly P.V. Sri Ramya Routhu SunithaRani C. Ganesh Kumar Ahmed Kamal Mohammed Arifuddin 《Tetrahedron letters》2017,58(49):4632-4637
A simple and expedient multicomponent protocol was developed to synthesize 4-thiazolidinones by employing VOSO4 as a catalyst under ultrasonic irradiation. The significant features of this protocol includes shorter reaction time, high yields, low catalyst loading, and also the catalyst can be recovered and reused up to next four cycles without significant loss in catalytic activity. All the synthesized novel indazole compounds were evaluated for their antibacterial and anti-biofilm activities. Compounds 9n, 9o and 9q showed promising activity (MIC value of 3.9?µg/mL) against K. planticola (MTCC 530). They also exhibited significant bactericidal activity against K. planticola (MTCC 530) (MBC value of 15.6?µg/mL). Additionally, 9n, 9o and 9q inhibited biofilm formation (IC50 values ranging between 20.28–20.79?μg/mL) in this organism. 相似文献
24.
25.
为了提高镀层的表面质量,提出了一种超声辅助电镀的方法。超声的空化与搅拌作用可以影响电镀的电沉积过程。设计了合理的换能器结构,并搭建了超声辅助电镀装置。通过对模型进行压电声学场与电镀场耦合仿真分析,结果表明:在硫酸铜电解液,镀铜时间60s,电压300V条件下,进行超声辅助电镀,镀层厚度分布均匀,镀层中部电流密度分布均匀,边缘最大电流密度是未加超声的2倍左右 。基于仿真结果,进行相同的实验测试,结果表明:超声辅助电镀可以提高镀层的均匀性,减少铜颗粒表面的杂质,提高表面的光洁度。阴极样品距离换能器头部位置在60mm左右,镀层质量良好。 相似文献
26.
超声相控阵技术是目前聚乙烯管道热熔接头内部缺陷检测的一种主流方法。提出了基于注意力机制的改进Faster-RCNN目标检测网络用于超声相控阵D扫图聚乙烯管接头内部缺陷检测。针对聚乙烯管道热熔接头内部超声相控阵D扫图小缺陷较多、特征信息容易丢失的问题,将残差网络(ResNet50)与特征金字塔网络(FPN)相结合作为骨干网络,并引入卷积注意力模块(CBAM)自适应细化特征。将SSD网络框架和Faster-RCNN网络框架用于模型训练和测试,使用VGG16、ResNet50、ResNet50+FPN、ACBM+ResNet50+FPN作为骨干网络依次对超声相控阵聚乙烯管道热熔对接接头内部缺陷样本进行训练对比。结果表明,改进的Faster-RCNN网络模型在聚乙烯管接头内部缺陷检测和分类方面有明显改进,对小缺陷的检测性能有了显著的提高。 相似文献
27.
This paper follows our earlier work where a strong high frequency pressure peak has been observed as a consequence of the formation of shock waves due to the collapse of cavitation bubbles in water, excited by an ultrasonic source at 24 kHz. We study here the effects of liquid physical properties on the shock wave characteristics by replacing water as the medium successively with ethanol, glycerol and finally a 1:1 ethanol–water solution. The pressure frequency spectra obtained in our experiments (from more than 1.5 million cavitation collapsing events) show that the expected prominent shockwave pressure peak was barely detected for ethanol and glycerol, particularly at low input powers, but was consistently observed for the 1:1 ethanol–water solution as well as in water, with a slight shift in peak frequency for the solution. We also report two distinct features of shock waves in raising the frequency peak at MHz (inherent) and contributing to the raising of sub-harmonics (periodic). Empirically constructed acoustic pressure maps revealed significantly higher overall pressure amplitudes for the ethanol–water solution than for other liquids. Furthermore, a qualitative analysis revealed that mist-like patterns are developed in ethanol–water solution leading to higher pressures. 相似文献
28.
考虑压电材料非线性本构关系,建立了旋转式超声电机定子的非线性动力学模型,利用解析与数值方法研究超声电机定子的主共振响应,以揭示压电材料非线性本构关系对定子振动特性的影响,为深入研究旋转行波超声电机的动力学机理奠定基础. 相似文献
29.
A method for characterizing texture from measurements of ultrasonic wave velocities is proposed. In polycrystalline aggregates, ultrasonic wave velocities are strongly affected by orientation distribution coefficients (ODCs), which are usually used to describe the degree of preferred grain orientation in textured materials. In this work, velocities of longitudinal and transverse waves propagating into aluminum alloy 6061 were measured under pure shear, simple shear and uniaxial tension. From the measured ultrasonic wave velocities, the ODCs W400 and W420 were calculated to infer the deformation-induced texture. The predicted pole figures, obtained using ultrasonic velocities, were in good qualitative agreement with the finite element polycrystal model analyzed pole figures. 相似文献
30.
To date, there is no method to measure non-destructively the modulus of trabeculae within cancellous bone, whilst retaining
its structural integrity. In this study ultrasonic scanning, coupled with microCT imaging, is employed to determine trabeculae
modulus along the three major anatomical axes non-destructively. The proposed method allows cancellous bone specimens to remain
intact, for possible use in subsequent studies. Volume rendering of the microCT images allows three-dimensional visualization
of cancellous bone specimens to be tested. This facilitates trabeculae selection and accurate measurement of distance traveled
by the ultrasonic wave, thus yielding a good degree of confidence in the acoustic velocity measured. For all the three principal
anatomical directions, the measured acoustic speeds ranged from 2,115 to 3,077 m/s, giving an average of 2,505 m/s. Average
wave velocities in the superior–inferior, medial–lateral and anterior–posterior anatomical directions were found to be 2,295,
2,469 and 2,754 m/s, respectively; the differences corresponding to the three directions do not appear to be significant.
Subsequently, the modulus was then determined using elastic wave propagation theory. 相似文献